CORROSIONOFFERROUSMETALS CORROSION OF FERROUS METALS

One of the most familiar types of corrosion is ferrous oxide (rust), generally resulting from atmospheric oxidation of steel surfaces. Some metal oxides protect the underlying base metal, but rust is not a protective coating in any sense of the word. Its presence actually promotes additional attack by attracting moisture from the air and acting as a catalyst in causing additional corrosion to take place. As a result, all rust must be removed from steel surfaces, if complete control of the corrosive attack is to be realized.

Rust first shows on boltheads, holddown nuts, or other unprotected aircraft hardware. Its presence in these areas is generally not dangerous and has no immediate effect on the structural strength of any major components. However, it is indicative of a need for maintenance and of possible corrosive attack in more critical areas. It is also a factor in the general appearance of the equipment. When paint failures occur or mechanical damage exposes highly stressed steel surfaces to the atmosphere, even the smallest amount of rusting is potentially dangerous in these areas and must be removed and controlled.

Mechanical Removal of Iron Rust

The most practicable means of controlling the corrosion of steel is the complete removal of corrosion products by mechanical means and restoring corrosion preventive coatings. Except on highly stressed steel surfaces, the use of abrasive papers and compounds, small power buffers and buffing compounds, hand wire brushing, or steel wool are all acceptable cleanup procedures. However, it should be recognized that in any such use of abrasives, residual rust usually remains in the bottom of small pits and other crevices. It is practically impossible to remove all corrosion products by abrasive or polishing methods alone. As a result, once a part has rusted it usually corrodes again more easily than it did the first time.

Chemical Surface Treatment of Steel

There are approved methods for converting active rust to phosphates and other protective coatings. Parco Lubrizing and the use of other phosphoric acid proprietary chemicals are examples of such treatments. However, these processes require shop installed equipment and are impracticable for field use. Other commercial preparations are effective rust converters where tolerances are not critical and where thorough rinsing and neutralizing of residual acid is possible. These situations are generally not applicable to assembled aircraft, and the use of chemical inhibitors on installed steel parts is not only undesirable but very dangerous. The danger of entrapment of corrosive solutions and the resulting uncontrolled attack which could occur when such materials are used under field conditions outweigh any advantages to be gained from their use.

Removal of Corrosion From Highly Stressed Steel Parts

Any corrosion on the surface of a highly stressed steel part is potentially dangerous, and the careful removal of corrosion products is required. Surface scratches or change in surface structure from overheating can also cause sudden failure of these parts. Corrosion products must be removed by careful processing, using mild abrasive papers such as rouge or fine grit aluminum oxide, or fine buffing compounds on cloth buffing wheels. It is essential that steel surfaces not be overheated during buffing. After careful removal of surface corrosion, protective paint finishes should be reapplied immediately.